Analysis of the Effect of Adding Jatropha Seed Shell on the Physical and Thermal Properties of Recycled Polypropylene Composites

Authors

  • Via Siti Masluhah Politeknik STMI Jakarta
  • Enjelika Br Sembiring Politeknik STMI Jakarta
  • Chinta Radjeli Putri Nasution Politeknik STMI Jakarta
  • Reviana Inda Dwi Suyatmo Politeknik STMI Jakarta
  • Teguh Budi Santoso Politeknik STMI Jakarta

DOI:

https://doi.org/10.33096/jcpe.v9i3.1487

Keywords:

Alkalization, Degree of Crystallinity, Jatropha Seed Shell, MFR, Recycled Polypropylene

Abstract

The increasing volume of plastic waste, particularly polypropylene (PP), poses a significant environmental challenge. Recycling is a crucial solution but often leads to degradation of PP's mechanical and thermal properties of PP. This study aims to enhance recycled PP quality by adding a natural filler in the form of Jatropha Seed Shell (JSS). JSS is a potential filler due to its good mechanical and thermal properties, low density, and recyclability. The research was conducted in two parts: first, without alkalization treatment, using recycled PP with varying JSS additions at 0%, 5%, 10%, 15%, and 20%. The Melt Flow Rate (MFR) test without JSS showed an average value of 20.620 g/10 minutes, decreasing to 15.380 g/10 minutes at 20% JSS. JSS addition also increased crystallinity from 30.92% to 36.14% and melting temperature from 163.9°C to 166.4°C with 20% JSS. The second part, with alkalization treatment using a 20% NaOH solution, aimed to improve JSS compatibility with the PP matrix.  The results showed that alkalization treatment improved the distribution of the filler within the matrix, leading to enhanced mechanical and thermal properties. The MFR value decreased more significantly in this treatment compared to without alkalization, with the lowest value at 14.55 g/10 minutes in the composite with 20% JSS. The degree of crystallinity increased to 33.9% with 15% JSS addition, while the melting temperature remained stable.

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References

A. Alsabri, F. Tahir, and S. G. Al-Ghamdi, “Environmental impacts of polypropylene (PP) production and prospects of its recycling in the GCC region,” Mater Today Proc, vol. 56, pp. 2245–2251, 2022, doi: 10.1016/j.matpr.2021.11.574.

S. Saikrishnan, D. Jubinville, C. Tzoganakis, and T. H. Mekonnen, “Thermo-mechanical degradation of polypropylene (PP) and low-density polyethylene (LDPE) blends exposed to simulated recycling,” Polym Degrad Stab, vol. 182, p. 109390, Dec. 2020, doi: 10.1016/j.polymdegradstab.2020.109390.

D. J. E, O. S. N, and N. S. C, “Potentials of castor seed shell as a reinforcement in aluminum matrix composite development,” 2021.

O. A. Ogah, M. N. Joseph, O. U. Pauline, and F. O. Ohoke, “Development of Green Composites Based on Castor Bean Shell (Ricinus communis) as Filler in Epoxy Resin Polymer,” Journal of Fibers and Polymer Composites, vol. 3, no. 1, pp. 1–19, Mar. 2024, doi: 10.55043/jfpc.v3i1.156.

D. W. Nurhajati, M. Sholeh, I. N. Indrajati, and I. Setyorini, “Pengaruh bahan pengisi serat kaca terhadap sifat fisik dan kristalinitas polipaduan PC/ABS,” Majalah Kulit, Karet, dan Plastik, vol. 33, no. 1, p. 43, Jun. 2017, doi: 10.20543/mkkp.v33i1.2770.

A. Kufel and S. Kuciel, “Composites based on polypropylene modified with natural fillers to increase stiffness,” Czasopismo Techniczne, vol. 1, pp. 187–195, 2019, doi: 10.4467/2353737XCT.19.013.10053.

K. Friedrich and A. A. Almajid, “Manufacturing Aspects of Advanced Polymer Composites for Automotive Applications,” Applied Composite Materials, vol. 20, no. 2, pp. 107–128, Apr. 2013, doi: 10.1007/s10443-012-9258-7.

F. Romero, Z. Ortega, J. Castellano, A. N. Benítez, M. D. Marrero, and L. Suárez, “Use of Ricinus communis shredded material as filler in rotational molded parts to improve the bio-disintegration behavior,” Polymer Bulletin, vol. 80, no. 10, pp. 11295–11316, Oct. 2023, doi: 10.1007/s00289-022-04593-5.

K. K. Chawla, Composite Materials. New York, NY: Springer New York, 2012. doi: 10.1007/978-0-387-74365-3.

“Standard Test Method for Melt Flow Rates of Thermoplastics by Extrusion Plastometer 1”, doi: 10.1520/D1238-2.

“Test Method for Transition Temperatures and Enthalpies of Fusion and Crystallization of Polymers by Differential Scanning Calorimetry,” Sep. 01, 2021, ASTM International, West Conshohocken, PA. doi: 10.1520/D3418-21.

B. Maryanti and ) A As’ad Sonief, “Pengaruh Alkalisasi Komposit Serat Kelapa-Poliester Terhadap Kekuatan Tarik,” 2011.

C. Borsoi, M. A. Dahlem Júnior, L. V. R. Beltrami, B. Hansen, A. J. Zattera, and A. L. Catto, “Effects of alkaline treatment and kinetic analysis of agroindustrial residues from grape stalks and yerba mate fibers,” J Therm Anal Calorim, vol. 139, no. 5, pp. 3275–3286, Mar. 2020, doi: 10.1007/s10973-019-08666-y.

U. H. Hasyim, A. Yansah, and M. F. Nuris, “Modifikasi Sifat Kimia Serbuk Tempurung Kelapa (Stk) Sebagai Matriks Komposit Serat Alam Dengan Perbandingan Alkalisasi Naoh Dan KOH,” 2018.

M. A. Mohamed, J. Jaafar, A. F. Ismail, M. H. D. Othman, and M. A. Rahman, “Fourier Transform Infrared (FTIR) Spectroscopy,” in Membrane Characterization, Elsevier, 2017, pp. 3–29. doi: 10.1016/B978-0-444-63776-5.00001-2.

A. A. Psyanchin, E. M. Zakharova, and V. P. Zakharov, “Effect of melt flow modifier on the physico-mechanical properties of a polymer composite based on secondary polypropylene and aluminosilicate microspheres,” Perspektivnye Materialy, vol. 11, pp. 47–52, 2022, doi: 10.30791/1028-978X-2022-11-47-52.

L. Yan, N. Chouw, and X. Yuan, “Improving the mechanical properties of natural fibre fabric reinforced epoxy composites by alkali treatment,” Journal of Reinforced Plastics and Composites, vol. 31, no. 6, pp. 425–437, Mar. 2012, doi: 10.1177/0731684412439494.

A. Oushabi, S. Sair, F. Oudrhiri Hassani, Y. Abboud, O. Tanane, and A. El Bouari, “The effect of alkali treatment on mechanical, morphological and thermal properties of date palm fibers (DPFs): Study of the interface of DPF–Polyurethane composite,” S Afr J Chem Eng, vol. 23, pp. 116–123, Jun. 2017, doi: 10.1016/j.sajce.2017.04.005.

U. Nirmal, S. T. W. Lau, and J. Hashim, “Interfacial Adhesion Characteristics of Kenaf Fibres Subjected to Different Polymer Matrices and Fibre Treatments,” J Compos, vol. 2014, pp. 1–12, Nov. 2014, doi: 10.1155/2014/350737.

J. L. Rivera-Armenta, B. A. Salazar-Cruz, A. C. Espindola-Flores, D. S. Villarreal-Lucio, C. M. De León-Almazán, and J. Estrada-Martinez, “Thermal and Thermomechanical Characterization of Polypropylene-Seed Shell Particles Composites,” Applied Sciences, vol. 12, no. 16, p. 8336, Aug. 2022, doi: 10.3390/app12168336.

J. L. Rivera-Armenta, B. A. Salazar-Cruz, A. C. Espindola-Flores, D. S. Villarreal-Lucio, C. M. De León-Almazán, and J. Estrada-Martinez, “Thermal and Thermomechanical Characterization of Polypropylene-Seed Shell Particles Composites,” Applied Sciences, vol. 12, no. 16, p. 8336, Aug. 2022, doi: 10.3390/app12168336.

J. Z. Liang, B. Li, and J. Q. Ruan, “Crystallization properties and thermal stability of polypropylene composites filled with wollastonite,” Polym Test, vol. 42, pp. 185–191, Apr. 2015, doi: 10.1016/j.polymertesting.2015.01.017.

I. A. Idowu and O. O. Ilori, “Effect of fillers on mechanical properties of recycled low density polyethylene composites under weathered condition,” Nigerian Journal of Technological Research, vol. 15, no. 3, pp. 44–49, Nov. 2020, doi: 10.4314/njtr.v15i3.6.

S. Chandra Dubey, V. Mishra, and A. Sharma, “A review on polymer composite with waste material as reinforcement,” Mater Today Proc, vol. 47, pp. 2846–2851, 2021, doi: 10.1016/j.matpr.2021.03.611.

S. P. Dwivedi and G. Dwivedi, “Utilization of Organic Waste and Inorganic Waste in Development of Green Hybrid Composite Material,” Mater Perform Charact, vol. 8, no. 1, pp. 316–328, Jul. 2019, doi: 10.1520/MPC20190023.

L. Yan, N. Chouw, and X. Yuan, “Improving the mechanical properties of natural fibre fabric reinforced epoxy composites by alkali treatment,” Journal of Reinforced Plastics and Composites, vol. 31, no. 6, pp. 425–437, Mar. 2012, doi: 10.1177/0731684412439494.

E. Yuanita, Y. A. Husnil, M. A. Mochtar, R. Lailani, and M. Chalid, “The Effect of Alkalization Treatment on Fiber-Matrix Compatibility in Natural Fiber Reinforced Composite,” Key Eng Mater, vol. 847, pp. 28–33, Jun. 2020, doi: 10.4028/www.scientific.net/KEM.847.28.

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Published

01-07-2025

How to Cite

Analysis of the Effect of Adding Jatropha Seed Shell on the Physical and Thermal Properties of Recycled Polypropylene Composites. (2025). Journal of Chemical Process Engineering, 9(3), 183-192. https://doi.org/10.33096/jcpe.v9i3.1487